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B.R.S.M — An organic chemistry blog

B.R.S.M. — A blog about total synthesis, organic synthesis and chemical history

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B.R.S.M — An organic chemistry blog | brsmblog.com Reviews

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B.R.S.M. — A blog about total synthesis, organic synthesis and chemical history

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About — B.R.S.M.

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Tet Lett. Is other people. Feel free to email me with suggestions, feedback, ideas for guest posts, beer recipes or about absolutely anything:. If you'd rather have a conversation in 160 character chunks, or be subjected to my random thoughts between posts, you can follow me on Twitter:. And you should probably take everything I say with a large pinch of salt and take the usual precautions. Subscribe to comments on this post ). November 19th, 2011 - 12:21. January 14th, 2012 - 18:14. My source heard it f...

2

Literature Archives @ B.R.S.M.

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DiRocco’s Electrochemical Series of Photocatalysts. Catalyst from the latest MacMillan group paper? Don't look at me like that it's commercially available from Aldrich.[1] And you can remember its oxidation potential, right? Versus the Saturated Calomel Electrode. In the Ir(iii)* excited state. As Ir(iv) after reductive quenching? Electrochemical Series compiled by Daniel DiRocco of Merck. Click for large PNG image.*. Alternatively, here's a better quality version as a PDF. Angew Chem. Int. Ed. From - o...

3

Chemistry World: Organic Matter — B.R.S.M.

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The road to Tet. Lett. Is paved with good intentions. Chemistry World: Organic Matter. Fantastic artwork from the RSC. Paul Dochety's blog at Totallysynthetic.com. Think British C&EN, if you're not familiar with it). However, his tenure there has recently also come to an end. And to try to fill the organic-shaped hole in its opinion pages the RSC has commisioned a new column Organic Matter. As you've probably heard already. Authorship will be shared between myself, Karl Collins (of A Retrosynthetic Life.

4

Total Synthesis Archives @ B.R.S.M.

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The road to Tet. Lett. Is paved with good intentions. Maoecrystal V (Part 2: Zakarian/Davies). Enantioselective Synthesis of -Maoecrystal V by Enantiodetermining C H Functionalization. Armen Zakarian, Huw M. L. Davies. J Am Chem. Soc. This is the second part of my coverage of the two recently published syntheses of -maoecrystal V, dealing with the route completed jointly by the Davies and Zakarian groups (Part 1, featuring the Thomson group synthesis is here. This well-planned cycloaddition enabled the...

5

And Now For Something Completely Different 10: Don't Buy Your Undecacycloicosane From Sigma-Aldrich — B.R.S.M.

http://brsmblog.com/and-now-for-something-completely-different-10-dont-buy-your-undecacyclo10-8-0-0211-036-049-058-0710-01316-01419-01518-01720icosane-from-sigma-aldrich

And Now For Something Completely Different 10: Don’t Buy Your Undecacycloicosane From Sigma-Aldrich. A funny thing happened the other day: I went onto the Sigma-Aldrich website to order some undecacyclo[10.8.0.0(2,11).0(3,6).0(4,9).0(5,8).0(7,10).0(13,16).0(14,19).0(15,18).0(17,20)]icosane, and was amused to notice a rather M. C. Escher-like rendering of the structure:. More serious posts soon! Subscribe to comments on this post ). March 3rd, 2014 - 16:12. What the hell is it for? March 3rd, 2014 - 22:47.

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Links - Labsolutely

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Wandering in the Lab (Beta 0.3). That’s my sunday morning reading (in a kind of alphabetic order):. Chemistry is the Answer. McSweeney’s Internet Tendency. Try This at Home. Leave a Reply Cancel reply. My wanders on Twitter. CoverTime: may the cubane be with you. Fear of the Duck. Microfluidics Galore (and ranting). ISMSC 2015 – Strasbourg. For a fistful of pics. American Dad’s chemistry. Videogames and science #2 “Dying Light”. Pics] For Your Chemists: HCL: I Choose You! On CoverTime: 80s vs 90s.

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Finding Teaching Skills in Unexpected Places | Cheersical Education

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All things chemical education: research, practice, theory, and more. New Vistas in Reaction Kinetics. Finding Teaching Skills in Unexpected Places. Developing Concepts in General Chemistry; Symposium on Chemistry MOOCs. Organic Chemistry Curriculum: A Step in the Right Direction. What Does “Inquiry” Mean? Adventures in the Midwest. Techniques in Learning and Teaching. June 3, 2015. Finding Teaching Skills in Unexpected Places. The other day as I was recording a video. No planes of symmetry at all. Brute ...

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Blog Syn: February 2013

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Crowdsourcing meets Organic Synthesis. Speed and Aplomb. Monday, February 18, 2013. Blog Syn #003: Benzylic Oxidation of Arylmethanes by IBX. 2/27/13 - Added Tamsyn NMR and email. 2/25/13 - Added Phil NMR and email. Nicolaou, K. C. Montagnon, T. Baran, P. S. Zhong, Y. L. J. Am. Chem. Soc. Three - B.R.S.M. And coworker (United Kingdom), See Arr Oh. Somewhere, U.S.A.). Pending Blog Syn repeat. Initial - Difficult to reproduce. Little / no product observed or isolated. A day in the library can save you a we...

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Chartier | The IP Alchemist Chartier | Patent law, chemistry, language and more

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Skip to main content. Skip to secondary content. Patent law, chemistry, language and more. Posts Tagged ‘Chartier’. An Alchemist in Paris – Dining III. May 10, 2015. On Chemophobia and the Chemical-Free Bear. Shamnad on The vigil for Orlando – thoughts from a gay man in London. On The vigil for Orlando – thoughts from a gay man in London. Andrew on The vigil for Orlando – thoughts from a gay man in London. On Chemophobia and the Chemical-Free Bear. Tweets by @EIP Elements. Better Living Through Chemistry.

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Publications | The IP Alchemist Publications | Patent law, chemistry, language and more

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Skip to main content. Skip to secondary content. Patent law, chemistry, language and more. My professional and other publications will be added here. Journal of Intellectual Property Law and Practice ( JIPLP. In 2013. Incidentally, JIPLP has its own blog. Featuring editorials and some of the articles. A Principle of General Application read about it here. Lions in the path or paper tigers? Read about it here. Samsung v Apple How does the judge become an Informed User? Read about it here. Routine rejectio...

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Ma Bourgogne | The IP Alchemist Ma Bourgogne | Patent law, chemistry, language and more

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Skip to main content. Skip to secondary content. Patent law, chemistry, language and more. Posts Tagged ‘Ma Bourgogne’. An Alchemist in Paris – Dining II. May 10, 2015. So on Easter Day it was time for suggestion number 2 from Andrew - Ma Bourgogne. Also conveniently close to my hotel (are you seeing a pattern? A few minutes later]. Anyway I went for a new one on me. Bleu des Causses. I was hoping for something very strong but it was surprisingly mild for being both blue and goat milk. It was...The resta...

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Cat Cafe | The IP Alchemist Cat Cafe | Patent law, chemistry, language and more

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Skip to main content. Skip to secondary content. Patent law, chemistry, language and more. Posts Tagged ‘Cat Cafe’. An Alchemist in Paris – the Café Des Chats Bastille. May 10, 2015. So having sneaked a photo at the cat cafe I had to come in. There are loads of cats – apparently 12 in total but three lined up by me. It is adorable. Inside the Cat Cafe. More Inside the Cat Cafe. On Chemophobia and the Chemical-Free Bear. Shamnad on The vigil for Orlando – thoughts from a gay man in London.

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An Alchemist in Paris – postcards from the Louvre | The IP Alchemist An Alchemist in Paris – postcards from the Louvre | Patent law, chemistry, language and more

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Skip to main content. Skip to secondary content. Patent law, chemistry, language and more. An Alchemist in Paris – postcards from the Louvre. May 10, 2015. All timings are approximate…. Making better progress – seen the two special exhibitions and particularly bowled over by Poussin. Need more restorative rest and then I will tackle Middle Ages and Egypt. In that order. After that I will probably have had enough. Overheard in the Louvre – viewing through a magnifying glass a paten with an exquisite...

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Just look at the structure of this alkaloid! | The Heterocyclist

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A blog about heterocyclic chemistry. January 28, 2013. Just look at the structure of this alkaloid! Sometimes you just have to step back and marvel at the structures that are found in nature. Check out zamamiphidin A, a new manzamine alkaloid isolated from an Okinawan sponge by J. Kobayashi and co-workers ( Organic Letters. Heptacyclic. Quaternary ammonium. Massively bridged. Well done, sponges! Laquo; Previous post. Next post ». 7 responses to “Just look at the structure of this alkaloid! I guess when y...

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Uncategorized | The Heterocyclist

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A blog about heterocyclic chemistry. RSS for this section. April 29, 2013. Pd(II)-Catalyzed Dehydrogenative Cyclizations of. Near-simultaneous reports of an interesting new pyrrole (and dihydropyrrole) synthesis have appeared recently from the labs of Frank Glorius (Westfälische Wilhelms-Universität Münster). And Naohiko Yoshikai (Nanyang Technologial University, Singapore). The scope of the reaction is decent, as indicated below. Failures include R. Or cyclopropyl and R. February 4, 2013. I keep it upda...

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B.R.S.M — An organic chemistry blog

Maoecrystal V (Part 2: Zakarian/Davies). Enantioselective Synthesis of -Maoecrystal V by Enantiodetermining C H Functionalization. Armen Zakarian, Huw M. L. Davies. J Am Chem. Soc. This is the second part of my coverage of the two recently published syntheses of -maoecrystal V, dealing with the route completed jointly by the Davies and Zakarian groups (Part 1, featuring the Thomson group synthesis is here. I'm reusing this scheme because it took me an extremely long time to draw. This well-planned cycl...

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